Brian G. Cox
- Published in print:
- 2013
- Published Online:
- May 2013
- ISBN:
- 9780199670512
- eISBN:
- 9780199670512
- Item type:
- book
- Publisher:
- Oxford University Press
- DOI:
- 10.1093/acprof:oso/9780199670512.001.0001
- Subject:
- Physics, Condensed Matter Physics / Materials
Acids and bases are ubiquitous in chemistry. Our understanding of them, however, is dominated by their behaviour in water. Transfer to non-aqueous solvents leads to profound changes in acid-base ...
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Acids and bases are ubiquitous in chemistry. Our understanding of them, however, is dominated by their behaviour in water. Transfer to non-aqueous solvents leads to profound changes in acid-base strengths and to the rates and equilibria of many processes: for example, synthetic reactions involving acids, bases, and nucleophiles; isolation of pharmaceutical actives through salt formation; formation of zwitter-ions in amino acids; and chromatographic separation of substrates. This book seeks to enhance our understanding of acids and bases by reviewing and analysing their behaviour in non-aqueous solvents. The behaviour is related where possible to that in water, but correlations and contrasts between solvents are also presented. Fundamental background material is provided in the initial chapters: quantitative aspects of acid–base equilibria, including definitions and relationships between solution pH and species distribution; the influence of molecular structure on acid strengths; and acidity in aqueous solution. Solvent properties are reviewed, along with the magnitude of the interaction energies of solvent molecules with (especially) ions; the ability of solvents to participate in hydrogen bonding and to accept or donate electron pairs is seen to be crucial. Experimental methods for determining dissociation constants are described in detail. In the remaining chapters, dissociation constants of a wide range of acids in three distinct classes of solvent are discussed: protic solvents, such as alcohols, which are strong hydrogen-bond donors; basic, polar aprotic solvents, such as dimethylformamide; and low-basicity and low-polarity solvents, such as acetonitrile and tetrahydrofuran. Dissociation constants of individual acids vary over more than twenty orders of magnitude among the solvents, and there is a strong differentiation between the response of neutral and charged acids to solvent change. Ion-pairing and hydrogen-bonding equilibria, such as between phenol and phenoxide ions, play an increasingly important role as the solvent polarity decreases, and their influence on acid–base equilibria and salt formation is described.Less
Acids and bases are ubiquitous in chemistry. Our understanding of them, however, is dominated by their behaviour in water. Transfer to non-aqueous solvents leads to profound changes in acid-base strengths and to the rates and equilibria of many processes: for example, synthetic reactions involving acids, bases, and nucleophiles; isolation of pharmaceutical actives through salt formation; formation of zwitter-ions in amino acids; and chromatographic separation of substrates. This book seeks to enhance our understanding of acids and bases by reviewing and analysing their behaviour in non-aqueous solvents. The behaviour is related where possible to that in water, but correlations and contrasts between solvents are also presented. Fundamental background material is provided in the initial chapters: quantitative aspects of acid–base equilibria, including definitions and relationships between solution pH and species distribution; the influence of molecular structure on acid strengths; and acidity in aqueous solution. Solvent properties are reviewed, along with the magnitude of the interaction energies of solvent molecules with (especially) ions; the ability of solvents to participate in hydrogen bonding and to accept or donate electron pairs is seen to be crucial. Experimental methods for determining dissociation constants are described in detail. In the remaining chapters, dissociation constants of a wide range of acids in three distinct classes of solvent are discussed: protic solvents, such as alcohols, which are strong hydrogen-bond donors; basic, polar aprotic solvents, such as dimethylformamide; and low-basicity and low-polarity solvents, such as acetonitrile and tetrahydrofuran. Dissociation constants of individual acids vary over more than twenty orders of magnitude among the solvents, and there is a strong differentiation between the response of neutral and charged acids to solvent change. Ion-pairing and hydrogen-bonding equilibria, such as between phenol and phenoxide ions, play an increasingly important role as the solvent polarity decreases, and their influence on acid–base equilibria and salt formation is described.
Andrew Briggs and Oleg Kolosov
- Published in print:
- 2009
- Published Online:
- February 2010
- ISBN:
- 9780199232734
- eISBN:
- 9780191716355
- Item type:
- book
- Publisher:
- Oxford University Press
- DOI:
- 10.1093/acprof:oso/9780199232734.001.0001
- Subject:
- Physics, Condensed Matter Physics / Materials
Acoustic microscopy enables you to image and measure the elastic properties of materials with the resolution of a good microscope. By using frequencies in the microwave range, it is possible to make ...
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Acoustic microscopy enables you to image and measure the elastic properties of materials with the resolution of a good microscope. By using frequencies in the microwave range, it is possible to make the acoustic wavelength comparable with the wavelength of light, and hence to achieve a resolution comparable with an optical microscope. The contrast gives information about the elastic properties and structure of the sample. Since acoustic waves can propagate in materials, acoustic microscopy can be used for interior imaging, with high sensitivity to defects such as delaminations. Solids can support both longitudinal and transverse acoustic waves. At surfaces a combination of the two known as Rayleigh waves can propagate, and in many circumstances these dominate the contrast in acoustic microscopy. Contrast theory accounts for the variation of signal with defocus, V(z). Acoustic microscopy can image and measure properties such as anisotropy and features such as surface boundaries and cracks. A scanning probe microscope can be used to detect ultrasonic vibration of a surface with resolution in the nanometre range, thus beating the diffraction limit by operating in the extreme near‐field. This 2nd edition of Acoustic Microscopy has a major new chapter on the technique and applications of acoustically exited probe microscopy.Less
Acoustic microscopy enables you to image and measure the elastic properties of materials with the resolution of a good microscope. By using frequencies in the microwave range, it is possible to make the acoustic wavelength comparable with the wavelength of light, and hence to achieve a resolution comparable with an optical microscope. The contrast gives information about the elastic properties and structure of the sample. Since acoustic waves can propagate in materials, acoustic microscopy can be used for interior imaging, with high sensitivity to defects such as delaminations. Solids can support both longitudinal and transverse acoustic waves. At surfaces a combination of the two known as Rayleigh waves can propagate, and in many circumstances these dominate the contrast in acoustic microscopy. Contrast theory accounts for the variation of signal with defocus, V(z). Acoustic microscopy can image and measure properties such as anisotropy and features such as surface boundaries and cracks. A scanning probe microscope can be used to detect ultrasonic vibration of a surface with resolution in the nanometre range, thus beating the diffraction limit by operating in the extreme near‐field. This 2nd edition of Acoustic Microscopy has a major new chapter on the technique and applications of acoustically exited probe microscopy.
Robert Blinc
- Published in print:
- 2011
- Published Online:
- January 2012
- ISBN:
- 9780199570942
- eISBN:
- 9780191728631
- Item type:
- book
- Publisher:
- Oxford University Press
- DOI:
- 10.1093/acprof:oso/9780199570942.001.0001
- Subject:
- Physics, Condensed Matter Physics / Materials
The field of ferroelectricity has greatly expanded and changed recently. In addition to classical organic and inorganic ferroelectrics as well as composite ferroelectrics new fields and materials ...
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The field of ferroelectricity has greatly expanded and changed recently. In addition to classical organic and inorganic ferroelectrics as well as composite ferroelectrics new fields and materials have appeared, important for both basic science and application and showing technological promise for novel multifunctional devices. Most of these fields were unknown or inactive 20 to 40 years ago. Such new fields are multiferroic magnetoelectric systems, where the spontaneous polarization and the spontaneous magnetization are allowed to coexist, incommensurate ferroelectrics, where the periodicity of the order parameter is incommensurate to the periodicity of the underlying basic crystal lattice, ferroelectric liquid crystals, dipolar glasses, relaxor ferroelectrics, ferroelectric thin films and nanoferroelectrics. These new fields are in addition to basic physical interest also of great technological importance and allow for new memory devices, spintronic applications and electro‐optic devices. They are also important for applications in acoustics, robotics, telecommunications and medicine. New developments in relaxors allow for giant electromechanical and electrocaloric effects. The book is primarily intended for material scientists working in research or industry. It is also intended for graduate and doctoral students and can be used as a textbook in graduate courses. Finally, it should be useful for everybody following the development of modern solid‐state physics.Less
The field of ferroelectricity has greatly expanded and changed recently. In addition to classical organic and inorganic ferroelectrics as well as composite ferroelectrics new fields and materials have appeared, important for both basic science and application and showing technological promise for novel multifunctional devices. Most of these fields were unknown or inactive 20 to 40 years ago. Such new fields are multiferroic magnetoelectric systems, where the spontaneous polarization and the spontaneous magnetization are allowed to coexist, incommensurate ferroelectrics, where the periodicity of the order parameter is incommensurate to the periodicity of the underlying basic crystal lattice, ferroelectric liquid crystals, dipolar glasses, relaxor ferroelectrics, ferroelectric thin films and nanoferroelectrics. These new fields are in addition to basic physical interest also of great technological importance and allow for new memory devices, spintronic applications and electro‐optic devices. They are also important for applications in acoustics, robotics, telecommunications and medicine. New developments in relaxors allow for giant electromechanical and electrocaloric effects. The book is primarily intended for material scientists working in research or industry. It is also intended for graduate and doctoral students and can be used as a textbook in graduate courses. Finally, it should be useful for everybody following the development of modern solid‐state physics.
John Banhart (ed.)
- Published in print:
- 2008
- Published Online:
- May 2008
- ISBN:
- 9780199213245
- eISBN:
- 9780191707582
- Item type:
- book
- Publisher:
- Oxford University Press
- DOI:
- 10.1093/acprof:oso/9780199213245.001.0001
- Subject:
- Physics, Condensed Matter Physics / Materials
Tomography provides three-dimensional images of heterogeneous materials or engineering components, and offers an unprecedented insight into their internal structure. By using X-rays generated by ...
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Tomography provides three-dimensional images of heterogeneous materials or engineering components, and offers an unprecedented insight into their internal structure. By using X-rays generated by synchrotrons, neutrons from nuclear reactors, or electrons provided by transmission electron microscopes, hitherto invisible structures can be revealed which are not accessible to conventional tomography based on X-ray tubes. This book provides detailed descriptions of the recent developments in this field, especially the extension of tomography to materials research and engineering. The book is grouped into four parts: a general introduction into the principles of tomography, image analysis and the interactions between radiation and matter, and one part each for synchrotron X-ray tomography, neutron tomography, and electron tomography. Within these parts, individual chapters written by different authors describe important versions of tomography, and also provide examples of applications to demonstrate the capacity of the methods.Less
Tomography provides three-dimensional images of heterogeneous materials or engineering components, and offers an unprecedented insight into their internal structure. By using X-rays generated by synchrotrons, neutrons from nuclear reactors, or electrons provided by transmission electron microscopes, hitherto invisible structures can be revealed which are not accessible to conventional tomography based on X-ray tubes. This book provides detailed descriptions of the recent developments in this field, especially the extension of tomography to materials research and engineering. The book is grouped into four parts: a general introduction into the principles of tomography, image analysis and the interactions between radiation and matter, and one part each for synchrotron X-ray tomography, neutron tomography, and electron tomography. Within these parts, individual chapters written by different authors describe important versions of tomography, and also provide examples of applications to demonstrate the capacity of the methods.
Michael Bordag, Galina Leonidovna Klimchitskaya, Umar Mohideen, and Vladimir Mikhaylovich Mostepanenko
- Published in print:
- 2009
- Published Online:
- September 2009
- ISBN:
- 9780199238743
- eISBN:
- 9780191716461
- Item type:
- book
- Publisher:
- Oxford University Press
- DOI:
- 10.1093/acprof:oso/9780199238743.001.0001
- Subject:
- Physics, Condensed Matter Physics / Materials, Atomic, Laser, and Optical Physics
The subject of this book is the Casimir effect, i.e., a manifestation of zero-point oscillations of the quantum vacuum in the form of forces acting between closely spaced bodies. It is a purely ...
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The subject of this book is the Casimir effect, i.e., a manifestation of zero-point oscillations of the quantum vacuum in the form of forces acting between closely spaced bodies. It is a purely quantum effect. There is no force acting between neutral bodies in classical electrodynamics. The Casimir effect has become an interdisciplinary subject. It plays an important role in various fields of physics such as condensed matter physics, quantum field theory, atomic and molecular physics, gravitation and cosmology, and mathematical physics. Most recently, the Casimir effect has been applied to nanotechnology and for obtaining constraints on the predictions of unification theories beyond the Standard Model. The book assembles together the field-theoretical foundations of this phenomenon, the application of the general theory to real materials, and a comprehensive description of all recently performed measurements of the Casimir force, including the comparison between experiment and theory. There is increasing interest in forces of vacuum origin. Numerous new results have been obtained during the last few years which are not reflected in the literature, but are very promising for fundamental science and nanotechnology. The book provides a source of information which presents a critical assessment of all of the main results and approaches contained in published journal papers. It also proposes new ideas which are not yet universally accepted but are finding increasing support from experiment.Less
The subject of this book is the Casimir effect, i.e., a manifestation of zero-point oscillations of the quantum vacuum in the form of forces acting between closely spaced bodies. It is a purely quantum effect. There is no force acting between neutral bodies in classical electrodynamics. The Casimir effect has become an interdisciplinary subject. It plays an important role in various fields of physics such as condensed matter physics, quantum field theory, atomic and molecular physics, gravitation and cosmology, and mathematical physics. Most recently, the Casimir effect has been applied to nanotechnology and for obtaining constraints on the predictions of unification theories beyond the Standard Model. The book assembles together the field-theoretical foundations of this phenomenon, the application of the general theory to real materials, and a comprehensive description of all recently performed measurements of the Casimir force, including the comparison between experiment and theory. There is increasing interest in forces of vacuum origin. Numerous new results have been obtained during the last few years which are not reflected in the literature, but are very promising for fundamental science and nanotechnology. The book provides a source of information which presents a critical assessment of all of the main results and approaches contained in published journal papers. It also proposes new ideas which are not yet universally accepted but are finding increasing support from experiment.
Erich H. Kisi and Christopher J. Howard
- Published in print:
- 2008
- Published Online:
- January 2009
- ISBN:
- 9780198515944
- eISBN:
- 9780191705663
- Item type:
- book
- Publisher:
- Oxford University Press
- DOI:
- 10.1093/acprof:oso/9780198515944.001.0001
- Subject:
- Physics, Condensed Matter Physics / Materials
This book covers the theory, practicalities, and the extensive applications of neutron powder diffraction in materials science, physics, chemistry, mineralogy, and engineering. Various highlight ...
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This book covers the theory, practicalities, and the extensive applications of neutron powder diffraction in materials science, physics, chemistry, mineralogy, and engineering. Various highlight applications of neutron powder diffraction are outlined in the introduction, then the theory is developed and instrumentation described sufficient for a return to the applications. The book covers the use of neutron powder diffraction in the solution (hard) and refinement (more straightforward) of crystal and magnetic structures, applications of powder diffraction in quantitative phase analysis, extraction of microstructural information from powder diffraction patterns, and the applications of neutron diffraction in studies of elastic properties and for the measurement of residual stress. Additional theory to underpin these various applications is developed as required.Less
This book covers the theory, practicalities, and the extensive applications of neutron powder diffraction in materials science, physics, chemistry, mineralogy, and engineering. Various highlight applications of neutron powder diffraction are outlined in the introduction, then the theory is developed and instrumentation described sufficient for a return to the applications. The book covers the use of neutron powder diffraction in the solution (hard) and refinement (more straightforward) of crystal and magnetic structures, applications of powder diffraction in quantitative phase analysis, extraction of microstructural information from powder diffraction patterns, and the applications of neutron diffraction in studies of elastic properties and for the measurement of residual stress. Additional theory to underpin these various applications is developed as required.
Christopher Hammond
- Published in print:
- 2015
- Published Online:
- August 2015
- ISBN:
- 9780198738671
- eISBN:
- 9780191801938
- Item type:
- book
- Publisher:
- Oxford University Press
- DOI:
- 10.1093/acprof:oso/9780198738671.001.0001
- Subject:
- Physics, Crystallography, Condensed Matter Physics / Materials
This book provides an introduction to crystallography, light, X-ray, and electron diffraction. The book also shows, by historical and biographical references, how the subject has developed from the ...
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This book provides an introduction to crystallography, light, X-ray, and electron diffraction. The book also shows, by historical and biographical references, how the subject has developed from the work and insights of successive generations of crystallographers and scientists. The book shows how an understanding of crystal structures, both inorganic and organic may be built up from simple ideas of atomic and molecular packing. Beginning with (two-dimensional) examples of patterns and tilings, the concepts of lattices, symmetry point, and space groups are developed. ‘Penrose’ tilings and quasiperiodic structures are also included. The reciprocal lattice and its importance in understanding the geometry of light, X-ray, and electron diffraction patterns is explained in simple terms, leading to Fourier analysis in diffraction, crystal structure determination, image formation, and the diffraction-limited resolution in these techniques. Practical X-ray and electron diffraction techniques and their applications are described. A recurring theme is the common principles: the techniques are not treated in isolation.Less
This book provides an introduction to crystallography, light, X-ray, and electron diffraction. The book also shows, by historical and biographical references, how the subject has developed from the work and insights of successive generations of crystallographers and scientists. The book shows how an understanding of crystal structures, both inorganic and organic may be built up from simple ideas of atomic and molecular packing. Beginning with (two-dimensional) examples of patterns and tilings, the concepts of lattices, symmetry point, and space groups are developed. ‘Penrose’ tilings and quasiperiodic structures are also included. The reciprocal lattice and its importance in understanding the geometry of light, X-ray, and electron diffraction patterns is explained in simple terms, leading to Fourier analysis in diffraction, crystal structure determination, image formation, and the diffraction-limited resolution in these techniques. Practical X-ray and electron diffraction techniques and their applications are described. A recurring theme is the common principles: the techniques are not treated in isolation.
Mark Ladd
- Published in print:
- 2016
- Published Online:
- May 2016
- ISBN:
- 9780198729945
- eISBN:
- 9780191818783
- Item type:
- book
- Publisher:
- Oxford University Press
- DOI:
- 10.1093/acprof:oso/9780198729945.001.0001
- Subject:
- Physics, Condensed Matter Physics / Materials
This book is aimed at undergraduate students in both chemistry and those degree subjects in which chemistry forms a significant part. It does not reflect any particular academic year, and so finds a ...
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This book is aimed at undergraduate students in both chemistry and those degree subjects in which chemistry forms a significant part. It does not reflect any particular academic year, and so finds a place during the normal span of degree studies in the physical sciences. An A-level standard in science and mathematics is presumed; additional mathematical treatments are discussed in Appendices. An introductory first chapter leads into the main subject matter, which is treated through four chapters in terms of the principle bonding forces of cohesion in the solid state; a further chapter discusses nanosize materials. Important applications of the study topics are interspersed at appropriate points within the text. Each chapter is provided with a set of problems of varying degrees of difficulty, so as to assist the reader in gaining a facility with the subject matter and its applications. The problems are supplemented by detailed tutorial solutions, some of which present additional relevant material that indicate useful extensions of the topics. The acquisition of a three-dimensional visualization facility for chemical structures is aided by the provision of stereoscopic illustrations, and instructions for their correct viewing are provided. Computational aids are an important adjunct to both the understanding of the textual material and the solving of problems. A set of computer programs, some of which are interactive, has been devised for these applications and a short chapter provides additional information and practice in their execution. Notwithstanding chemical bonding and solid-state chemistry are wide-ranging topics, sufficient detail is included to form a sound basis for wider explorations of these subjects.Less
This book is aimed at undergraduate students in both chemistry and those degree subjects in which chemistry forms a significant part. It does not reflect any particular academic year, and so finds a place during the normal span of degree studies in the physical sciences. An A-level standard in science and mathematics is presumed; additional mathematical treatments are discussed in Appendices. An introductory first chapter leads into the main subject matter, which is treated through four chapters in terms of the principle bonding forces of cohesion in the solid state; a further chapter discusses nanosize materials. Important applications of the study topics are interspersed at appropriate points within the text. Each chapter is provided with a set of problems of varying degrees of difficulty, so as to assist the reader in gaining a facility with the subject matter and its applications. The problems are supplemented by detailed tutorial solutions, some of which present additional relevant material that indicate useful extensions of the topics. The acquisition of a three-dimensional visualization facility for chemical structures is aided by the provision of stereoscopic illustrations, and instructions for their correct viewing are provided. Computational aids are an important adjunct to both the understanding of the textual material and the solving of problems. A set of computer programs, some of which are interactive, has been devised for these applications and a short chapter provides additional information and practice in their execution. Notwithstanding chemical bonding and solid-state chemistry are wide-ranging topics, sufficient detail is included to form a sound basis for wider explorations of these subjects.
Lev Pitaevskii and Sandro Stringari
- Published in print:
- 2016
- Published Online:
- March 2016
- ISBN:
- 9780198758884
- eISBN:
- 9780191818721
- Item type:
- book
- Publisher:
- Oxford University Press
- DOI:
- 10.1093/acprof:oso/9780198758884.001.0001
- Subject:
- Physics, Condensed Matter Physics / Materials
This volume introduces the basic concepts of Bose–Einstein condensation and superfluidity. It makes special reference to the physics of ultracold atomic gases; an area in which enormous experimental ...
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This volume introduces the basic concepts of Bose–Einstein condensation and superfluidity. It makes special reference to the physics of ultracold atomic gases; an area in which enormous experimental and theoretical progress has been achieved in the last twenty years. Various theoretical approaches to describing the physics of interacting bosons and of interacting Fermi gases, giving rise to bosonic pairs and hence to condensation, are discussed in detail, both in uniform and harmonically trapped configurations. Special focus is given to the comparison between theory and experiment, concerning various equilibrium, dynamic, thermodynamic, and superfluid properties of these novel systems. The volume also includes discussions of ultracold gases in dimensions, quantum mixtures, and long-range dipolar interactions.Less
This volume introduces the basic concepts of Bose–Einstein condensation and superfluidity. It makes special reference to the physics of ultracold atomic gases; an area in which enormous experimental and theoretical progress has been achieved in the last twenty years. Various theoretical approaches to describing the physics of interacting bosons and of interacting Fermi gases, giving rise to bosonic pairs and hence to condensation, are discussed in detail, both in uniform and harmonically trapped configurations. Special focus is given to the comparison between theory and experiment, concerning various equilibrium, dynamic, thermodynamic, and superfluid properties of these novel systems. The volume also includes discussions of ultracold gases in dimensions, quantum mixtures, and long-range dipolar interactions.
Robert M. Mazo
- Published in print:
- 2008
- Published Online:
- January 2010
- ISBN:
- 9780199556441
- eISBN:
- 9780191705625
- Item type:
- book
- Publisher:
- Oxford University Press
- DOI:
- 10.1093/acprof:oso/9780199556441.001.0001
- Subject:
- Physics, Condensed Matter Physics / Materials
Brownian motion is the incessant motion of small particles immersed in an ambient medium. It is due to fluctuations in the motion of the medium particles on the molecular scale. The name has been ...
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Brownian motion is the incessant motion of small particles immersed in an ambient medium. It is due to fluctuations in the motion of the medium particles on the molecular scale. The name has been carried over to other fluctuation phenomena. This book treats the physical theory of Brownian motion. The extensive mathematical theory, which treats the subject as a subfield of the general theory of random processes, is touched on but not presented in any detail. Random or stochastic process theory and statistical mechanics are the primary tools. The first eight chapters treat the stochastic theory and some applications. The next six present the statistical mechanical point of view. Then follows chapters on applications to diffusion, noise, and polymers, followed by a treatment of the motion of interacting Brownian particles. The book ends with a final chapter treating simulation, fractals, and chaos.Less
Brownian motion is the incessant motion of small particles immersed in an ambient medium. It is due to fluctuations in the motion of the medium particles on the molecular scale. The name has been carried over to other fluctuation phenomena. This book treats the physical theory of Brownian motion. The extensive mathematical theory, which treats the subject as a subfield of the general theory of random processes, is touched on but not presented in any detail. Random or stochastic process theory and statistical mechanics are the primary tools. The first eight chapters treat the stochastic theory and some applications. The next six present the statistical mechanical point of view. Then follows chapters on applications to diffusion, noise, and polymers, followed by a treatment of the motion of interacting Brownian particles. The book ends with a final chapter treating simulation, fractals, and chaos.
“A Gentleman and an Officer”
‘A Nation of Beggars’?
The A Priori in Philosophy
A. J. Appasamy and his Reading of Rāmānuja
A. J. Tomlinson
Aaron Hill
The Abbey Theatre, 1899-1999
The Abbots and Priors of Late Medieval and Reformation England
Abelard and Heloise
